Novel High Free Volume Polymer, Addition Polytrimethylsilylnorbornene: Diffusion or Solubility Controlled Permeation
نویسنده
چکیده
This polymer is characterized by relatively high gas permeability, (Р(О2)=800 Barrer, Р(СО2)=4350 Barrer). It is interesting that for the series of gaseous alkanes С1-С4 permeability increases when the size of the penetrant increases and reaches the value Р(С4Н10)=17500 Barrer (at 1 atm). It is also noteworthy that this polymer keeps high permselectivity in separation of the mixture butane/methane (α(С4/С1)=22) which is close to the ideal separation factors for this gas pair [1]. This is quite unusual because permselectivity in mixed gas separation often decreases due to plasticization phenomena
منابع مشابه
In Silico Determination of Gas Permeabilities by Non-Equilibrium Molecular Dynamics: CO2 and He through PIM-1
We study the permeation dynamics of helium and carbon dioxide through an atomistically detailed model of a polymer of intrinsic microporosity, PIM-1, via non-equilibrium molecular dynamics (NEMD) simulations. This work presents the first explicit molecular modeling of gas permeation through a high free-volume polymer sample, and it demonstrates how permeability and solubility can be obtained co...
متن کاملEnhanced Controlled Transdermal Delivery of Mexazolam Using Ethylene-vinyl Acetate
Repeated oral administration of mexazolam, an anti-anxiety agent, may cause adverse effects such as gastric disturbance, drowsiness, and ataxia due to transiently high blood levels. Transdermal administration would avoid the systemic side effects and gastric disorders after oral administration. We have developed a matrix using ethylene-vinyl acetate (EVA), a heat-processible and flexible mat...
متن کاملEnhanced Controlled Transdermal Delivery of Mexazolam Using Ethylene-vinyl Acetate
Repeated oral administration of mexazolam, an anti-anxiety agent, may cause adverse effects such as gastric disturbance, drowsiness, and ataxia due to transiently high blood levels. Transdermal administration would avoid the systemic side effects and gastric disorders after oral administration. We have developed a matrix using ethylene-vinyl acetate (EVA), a heat-processible and flexible mat...
متن کاملMechanistic insight into highly efficient gas permeation and separation in a shape-persistent ladder polymer membrane.
A fully atomistic simulation study is reported to provide mechanistic insight into the superior performance experimentally observed for a polymer membrane (Carta et al., Science, 2013, 339, 303-307). The membrane namely PIM-EA-TB is produced by a shape-persistent ladder polymer of intrinsic microporosity (PIM) with rigid bridged bicyclic ethanoanthracene (EA) and Tröger's base (TB). The simulat...
متن کاملGas Permeation Properties of Hydroxyl-Group Containing Polyimide Membranes
A series of hydroxyl-group containing polyimides (HPIs) were prepared in order to investigate the structure-gas permeation property relationship. Each polymer membrane had structural characteristics that varied according to the dianhydride monomers. The imidization processes were monitored using spectroscopic and thermog-ravimetric analyses. The single gas permeability of He, H 2 , CO 2 , O 2 ,...
متن کامل